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That is not an air conditioner. An air conditioner needs a compressor, evaporator and condenser, this has none of them. What you have is a desktop evaporative cooler. Your theory of how it works is correct, the energy to evaporate the water is pulled from the air, that cools the air. But yes, the heat and moist air still stays in the room. Note, this only works in places with DRY air. If you are in a tropical location with humidity, this will not work because the air is already close to saturation with water.
There are large rooftop versions of this called swamp coolers, installed in places that have short hot dry summers, they work because the heat is still transported outside the building.
I'm renting a house with a swamp cooler. I'm sure they can be nice, but the effectiveness of mine ranges from "barely" to "not at all."