Battery capacity really doesn't have much to do with battery usage. Just how much the battery can hold compared to when it was new. I used to have a Series 4 with 83% capacity and it would last me 20 hours on WatchOS 10. I upgraded to a Series 9 and gave the 4 to my spouse. It might last them 12 hours but they have a lot more notifications activated on it and use it for Siri extensively.
Your usage, notifications, and background apps installed are what eat your battery. Unfortunately, the watch doesn't seem to report the apps using the most power like other devices. This means you have to use trial and error to try and reduce usage the most.