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How would it go if they were mixed and ignited?
Diesel burns slowly, though petrol makes diesel easier to ignite.
We mix them 3:1 Diesel/Petrol (called 'driptorch' fuel, used in 'driptorches') to safely put fire to the ground when we need to.
Source: am firefighter.
Never tried, but I would suspect that petrol could be an effective accelerant, as it'd reach its flash point long before the diesel does.